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Chemical Reaction Kinetics: Dissociation and Recombination of Diatomic Molecules (Demo)
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![]() | Overview and Learning ObjectivesThis model shows the dissociation and recombination of diatomic molecules. When the temperature rises, the diatomic bonds start to break, resulting in free radicals. When the temperature drops, the free radical starts to recombine and form diatomic bonds again. To provide the energy for dissociation and maintain the thermal stability of the recombined molecules, a heat bath is applied. This model can be used to explain a class of reactions, such as O2-->2O, H2-->2H. |
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![]() | Classroom PracticeA metaphor for students? Chemical reactions can be regarded as the processes of changing partners of atoms. A partnership between a pair of atoms is typically a covalent bond. The collision theory suggests that atoms bind with others, or lose partners, or swap partners, or do nothing when they collide. |
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![]() | Central ConceptsKey Concept: Chemical reactions result from making and breaking chemical bonds. The number of each kind of atom in a reaction remains constant. There are two types of two-body elementary reactions: breaking and making a bond. The rule for breaking a bond is simple: a bond is broken only when enough energy is given to a bonded party for escaping the potential well formed by its binding partner. Diatomic molecules that disassociate create free radicals. Free radicals react easily with molecules and other radicals. Additional Related ConceptsPhysics/Chemistry
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![]() | Textbook References
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![]() | Activity CreditsCreated by CC Project: CCATOMS using Molecular Workbench |
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![]() | Requirements
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Last Update: 11/25/2008
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These materials are based upon work supported
by the National Science Foundation under grant numbers
9980620, ESI-0242701 and EIA-0219345
Any opinions, findings, and conclusions or recommendations expressed in this
material are those of the author(s) and do not necessarily reflect
the views of the National Science Foundation.